Product ID:LIGROINE B.R. 35-50
MSDS Date:05/01/1991
FSC:6810
NIIN:00N033826
MSDS Number: BPTLZ

SPECTRUM CHEMICAL MFG CORP

14422 SOUTH SAN PEDRO ST
GARDENA, CA 90248-2027
US

Emergency Phone: 213-516-8000

Info Phone: 213-516-8000

Cage: 63415

SPECTRUM LABORATORY PRODUCTS INC

GARDENA, CA 90248-2027 US

Telephone: 310-516-9843

Cage: 63415

FLAMES/FLARES IN HAZ AREA. KEEP UNNECESSARY

RTECS: 9999999ZZ

CONTINOUS-FLOW MODE; ANY SCBA W/FULL FACEPIECE

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IS ANY POSSIBILITY THAT AN EMPLOYEE'S

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AN EYE WASH FOUNTAIN W/IN IMMEDIATE WORK AREA FOR

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IF LG AMT (OVER 1 ML/KG) IS INGESTED &

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INCL WEAK, DIZZ, SLOW & SHALLOW RESPIRATION, CONVULS,

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NO

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& CNS DEPRESSANT.INGEST OF ALCOHOLIC BEVERAGES MAY

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PETROLEUM REFINERY WORKERS INDICATE PERSONS

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BE @ AN INCR RISK TO DEVELOPMENT OF BENIGN

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NO EVIDENCE OF CHEM REMAINS (15-20 MIN).

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OR SALINE, OCCAS LIFT LIDS, UNTIL NO EVIDENCE OF

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ONLY HYDROCARBONS THAT ARE SOLV FOR TOX

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CARE MUST BE USED TO PVNT ASPIR. GASTRIC LAVAGE

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SHOULD BE DONE W/IN 15 MIN. IN ABSENCE OF

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USING SYRUP OF IPECAC W/OUT INCR HAZ OF ASPIR

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SYMPTOMATICALLY & SUPPORTIVELY. GASTRIC LAVAGE

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NO SPEC ANTIDOTE. TREAT

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LIGROINE.PEL & TLV AS VM&P NAPHTHA

CAS: 8032-32-4

RTECS: OI6180000

Fraction By Weight: 100%

OSHA PEL 300 PPM;400 PPM STEL

ACGIH TLV: 300 PPM

TO FIRE.ISOLATE FOR 1/2 MILE IN ALL DIREC IF

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IF FLOW CAN BE STOPPED; USE H*2O IN FLOODING AMTS AS

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FLOODING AMTS OF H*2O. APPLY FROM AS FAR DIST AS

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AND FLASH BACK.

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LITTLE/NO INJURY ON DIRECT EXTERNAL CONT

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LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:INHAL: ACUTE: HIGH CONC MAY CAUSE
NAUS, VOMIT, COUGH, & PULM IRRIT PROGRESSING TO PULM EDEMA, BLOODY
SPUTUM & BRONCHIAL PNEUM W/FEVER & COUGH. PENEUMOTHORAX & EMPHYSEMA
MAY COMPLICATE RECOVERY. CNS DE PRESS, POSS LEAD TO PROFOUND COMA
W/INHIBITION OF DEEP TENDON REFLEXES MAY OCCUR. CHRONIC: RPTD/RPLNG
(EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ:EXPOS MAY CAUSE DIZZ/WEAK/WT LOSS,
ANEMIA, NERVOUSNESS, PAINS IN LIMBS, PERIPHERAL NUMB &
PARESTHESIAS. SKIN: ACUTE: IRRIT & DRY MAY OCCUR FROM DEFAT ACTION
OF LIQ. CHRONIC: RPTD/PRLNG CONT M AY CAUSE DERM. EYE: ACUTE: HIGH
VAP CONC MAY CAUSE IRRIT & RED. VARIOUS LIQ HYDROCARBONS OF
SUBSTANCE MAY CAUSE (ING 6)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:INHAL: REMOVE FROM EXPOS TO AREA OF FRESH AIR IMMED. IF BRTHG
HAS STOPPED, GIVE ARTF RESP. MAINTAIN AIRWAY & BLOOD PRESS &
ADMINISTER O*2 IF AVAIL. KEEP WARM & @ REST. TREAT SYMPTOMATICALLY
& SUPPORTI VELY. ADMIN OF O*2 SHOULD BE PERFORMED BY QUALIFIED
PERS. GET MED ATTN IMMED. SKIN: REMOVE CONTAMD CLTHG & SHOES IMMED.
WASH AFFECTED AREA W/SOAP/H*2O MILD DETERGENT & LG AMTS OF H*2O
UNTIL (ING 13)

Flash Point Method:CC
Flash Point:<73F,<23C
Extinguishing Media:DRY CHEMICAL, CO*2, WATER SPRAY/ALCOHOL-RESISTANT
FOAM. FOR LARGER FIRES, USE WATER SPRAY, FOG-ALCOHOL-RESISTANT
FOAM.
Fire Fighting Procedures:NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP. MOVE
CONTR FROM FIRE AREA IF YOU CAN DO SO W/OUT RISK. APPLY COOLING
H*2O TO SIDES OF CONTRS THAT ARE(SUPP DATA)
Unusual Fire/Explosion Hazard:DANGEROUS FIRE HAZ WHEN EXPOS TO
HEAT/FLAME. VAP-AIR MIXT ARE EXPLOS ABOVE FL PT. VAPS ARE HVR/AIR &
MAY TRAVEL A CONSIDERABLE DIST TO SOURCE OF IGNIT (ING 5)

Spill Release Procedures:SHUT OFF IGNIT SOURCES. STOP LEAK IF YOU CAN
DO SO W/OUT RISK. USE H*2O SPRAY TO REDUCE VAPS. SM SPILLS: TAKE UP
W/SAND/OTHER ABSORB MATL & PLACE INTO CONTRS FOR LATER DISP. LGR
SPILLS: DIKE FAR AHEAD OF SPILL FOR LATER DISP. NO SMOKING, (ING
21)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:NONE SPECIFIED BY MANUFACTURER.
Other Precautions:AVOID CONT W/HEAT/SPARKS/FLAMES/OTHER SOURCES OF
IGNIT. VAPS MAY BE EXPLOSIVE & POISONOUS; DO NOT ALLOW PERS IN
AREA. DO NOT OVERHEAT CONTRS; CONTRS MAY VIOLENTLY RUPTURE & TRAVEL
A CONSIDERABLE DISTA NCE IN HEAT OF FIRE.

Respiratory Protection:RESP SELECTION SHOULD BE BASED ON CONTAM LEVELS
& OPERATION. RESP MUST BE NIOSH/MSHA APPRVD: ANY TYPE 'C'
SUPPLIED-AIR RESP W/FULL FACEPIECE OPERATED IN PRESS-DEMAND/OTHER
POS PRESS MODE/W/FULL FACEPI ECE, HELMET/HOOD OPERATED IN (ING 22)
Ventilation:PROVIDE GEN DILUTION VENT TO MEET PUBLISHED EXPOS LIM. VENT
EQUIP MUST BE EXPLOSION-PROOF.
Protective Gloves:IMPERVIOUS GLOVES .
Eye Protection:CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:EMPLOYEE MUST WEAR APPROP PROT (IMPERVIOUS)
CLTHG & EQUIP TO PVNT RPTD/PRLNG SKIN CONT W/SUBSTANCE. WHERE THERE
(ING 23)
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
FIRE FIGHT PROC:EXPOS TO FLAME UNTIL WELL AFTER FIRE IS OUT. STAY AWAY
FROM ENDS OF TANKS. FOR MASSIVE FIRE IN CARGO AREA, USE UNMANNED
HOSE HOLDER/MONITOR NOZZ; IF THIS IS IMPOSSIBLE, WITHDRAW FROM A
REA & LET FIRE BURN. WITHDRAW IMMED IN CASE OF RISING SOUND FROM
VENTING SFTY DEVICE/ANY DISCOLORATION OF TANK DUE(ING2)

Boiling Pt:B.P. Text:95.0F,35.0C
Vapor Density:>1
Spec Gravity:<1
Solubility in Water:INSOLUBLE
Appearance and Odor:COLORLESS LIQUID WITH AN ODOR LIKE GASOLINE OR
KEROSENE

Stability Indicator/Materials to Avoid:YES
LIGROINE: NITROGEN TETROXIDE: POSSIBLE EXPLOSION. STRONG OXIDANTS:
EXTREMELY VIOLENT REACTIONS.
Stability Condition to Avoid:AVOID CONT W/HEAT/SPARKS/FLAMES OR OTHER
SOURCES OF IGNIT.
Hazardous Decomposition Products:THERMAL DECOMPOSITION PRODUCTS MAY
INCLUDE TOXIC CO*X.

Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH FEDERAL, STATE AND
LOCAL REGULATIONS .

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